{"id":89755,"date":"2022-09-21T15:04:02","date_gmt":"2022-09-21T15:04:02","guid":{"rendered":"https:\/\/www.bgs.ac.uk\/?p=89755"},"modified":"2024-02-26T09:15:12","modified_gmt":"2024-02-26T09:15:12","slug":"adventures-in-elemental-mapping-part-1-analysis-of-minerals","status":"publish","type":"post","link":"https:\/\/www.bgs.ac.uk\/news\/adventures-in-elemental-mapping-part-1-analysis-of-minerals\/","title":{"rendered":"Adventures in elemental mapping \u2013 part 1: analysis of minerals"},"content":{"rendered":"\n
\n

During the last year, the Inorganic Geochemistry (IG) Facility at the BGS headquarters in Nottingham installed a new laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS) system for the direct solids analysis of trace elements in geological, environmental and industrial materials. The system was selected with the aim of being able to map elemental distribution across these materials. In this blog, we will cover some highlights of working with the laser so far, focusing on our studies with BGS\u2019s economic geologist Eimear Deady on critical raw minerals from south-west England and mineralogist and petrographer Dr Alicja Lacinska on magnesium carbonate as a means of \u2018locking up\u2019 the potentially toxic element chromium.<\/p>\n\n\n\n

What is LA-ICP-MS?<\/h2>\n\n\n
\"Figure
\n\t\t\t\t\t
\n\t\t\t\t\t\t\"Information\n\t\t\t\t\t<\/div>\n\t\t\t\t\t

Figure 1: (a) Laser ablation of steel in air; the burning particles allow us to see their tracks. (b) Particle of steel filtered out of the gas stream after laser ablation. Simon Chenery BGS \u00a9 UKRI<\/p>\n<\/div>\n\t\t\t\t\t\n\t\t\t\t<\/figcaption><\/figure>\n\n\n

The laser in our LA-ICP-MS system samples less than one microgram of material by focusing the equivalent power of a nuclear power-generating station into a spot of light, less than the diameter of a human hair, for a mere ten billionths of a second. This intense burst of energy vaporises the tiny sample; we capture it in a stream of gas and pass it over to our mass spectrometer to analyse.<\/p>\n\n\n\n

For those who like technical specifications, the new LA system is an imageGEO193 from Elemental Scientific Lasers, which is designed for high-speed, high-resolution imaging of geological materials. it uses a 193 nm excimer laser, running at 1 to 500 Hz, and a fluence of 0 to 15 J\/cm2<\/sup>. The mass spectrometer is an 8900 series ICP-MS\/MS from Agilent Technologies. This generation of ICP-MS has high sensitivity and high selectivity, allowing us to measure fifty major elements, from per cent levels down to trace element concentrations below one part per million every fifth of a second.<\/p>\n\n\n\n

Importantly for users, it can make the laser ablation craters in either a circular or rectangular shape and between 1 and 150 microns across, which makes it ideal for mapping analysis. Solid samples can be used in almost any form, as long as they fit into the ablation chamber, although for mapping they need to have a flat, smooth surface. We would normally use samples that have been prepared in a similar way to those used for scanning electron microscope (SEM) or electron probe work, i.e. samples contained in either polished resin blocks or as thin sections. We use this preparation method because most geological samples are heterogeneous and require a nice cross-section to see what you are analysing.<\/p>\n\n\n

\"Figure
\n\t\t\t\t\t
\n\t\t\t\t\t\t\"Information\n\t\t\t\t\t<\/div>\n\t\t\t\t\t

Figure 2: The new imageGEO193 LA unit coupled to the 8900 series ICP-MS. Andrew Marriott (left) is operating the workstation computer whilst Elliott Hamilton (right) loads a new sample into the LA. The ICP-MS is in the background right. BGS \u00a9 UKRI<\/p>\n<\/div>\n\t\t\t\t\t\n\t\t\t\t<\/figcaption><\/figure>\n\n\n

The laser ablation mapping ablates across the whole surface of the sample, creating transect marks as shown on the SEM image in Figure 3. The process of ablating across the sample is sufficiently shallow that the sample is not disrupted for other future analytical work of a qualitative manner.<\/p>\n\n\n\t\t\t\t