UKCCSRC Call 1,2 paper: Understanding the solubility of water in carbon capture and storage mixtures: An FTIR spectroscopic study of H2O+CO2+N2 ternary mixtures

Dataset description

The solubility of water (H2O) in carbon dioxide (CO2) and nitrogen (N2) mixtures (xN2 = 0.050 and 0.100, mole fraction) has been investigated at 25 and 40 degrees C in the pressure range between 8 and 18 MPa. The motivation for this work is to aid the understanding of water solubility in complex CO2-based mixtures, which is required for the safety of anthropogenic CO2 transport via pipeline for carbon capture and storage (CCS) technology. The measurements have been performed using an FTIR spectroscopic approach and demonstrate that this method is a suitable technique to determine the concentration of water in both pure CO2 and CO2 + N2 mixtures. The presence of N2 lowers the mole concentration of water in CO2 by up to 42% for a given pressure in the studied conditions and this represents important data for the development of pipelines for CCS. This work also provides preliminary indications that the key parameters for the solubility of H2O in such CO2 + N2 mixtures are the temperature and the overall density of the fluid mixture and not solely the given pressure of the CCS mixture. This could have implications for understanding the parameters required to be monitored during the safer transportation of CO2 mixtures in CCS pipelines. The paper is available at http://www.sciencedirect.com/science/article/pii/S1750583615000444, DOI: 10.1016/j.ijggc.2015.02.002. UKCCSRC Grants UKCCSRC-C1-21 and UKCCSRC-C2-185.

Constraints

The dataset has been published as an open access journal article

Further information

For more information please contact:

Enquiries

Environmental Science Centre, Nicker Hill, Keyworth
Nottingham
NG12 5GG

Tel : +44 (0)115 936 3143
Fax :+44 (0)115 936 3276
Email :enquiries@bgs.ac.uk

Associated dataset(s)

UKCCSRC Call 1 Project: Determination of water solubility limits in CO2 mixtures to deliver water specification levels for CO2 transportation

Dataset details

Author(s) Stephanie Foltran , Mike George , Martyn Poliakoff
Principal Investigator(s) Stephanie Foltran
University of Nottingham
Mike George
University of Nottingham
Martyn Poliakoff
University of Nottingham
Language English
Curator British Geological Survey
Supply media/format Not available
Storage format Not available
Frequency of update not applicable
Start of capture {ts '2013-12-01 00:00:00'} Not known
End of capture {ts '2015-04-01 00:00:00'} April 2015
Online access URL http://www.sciencedirect.com/science/article/pii/S1750583615000444
Lineage statement See the journal publication for details
Supplementary information UKCCSRC Grants UKCCSRC-C1-21and UKCCSRC-C2-185
Constraints
Access constraints copyright (exclusive right to the publication, production, or sale of the rights to a literary, dramatic, musical, or artistic work, or to the use of a commercial print or label, granted by law for a specified period of time to an author, composer, artist, distributor)
Use constraints copyright (exclusive right to the publication, production, or sale of the rights to a literary, dramatic, musical, or artistic work, or to the use of a commercial print or label, granted by law for a specified period of time to an author, composer, artist, distributor)
Additional info on constraints The dataset has been published as an open access journal article
Contact details
Department Enquiries
Organisation British Geological Survey
Address Environmental Science Centre, Nicker Hill, Keyworth
City Nottingham
County Nottinghamshire
Country United Kingdom
Postcode NG12 5GG
E-mail enquiries@bgs.ac.uk
Telephone +44 (0)115 936 3143
Fax +44 (0)115 936 3276
Keywords
Topic category code (ISO) geoscientificInformation (information pertaining to earth sciences)
Keywords CARBON CAPTURE AND STORAGE
Keyword source BGS Keyphrases
Spatial details
Spatial Reference System Not available
Dataset extent
Coverage (Lat/Long) North boundary : 
East boundary  : 
South boundary : 
West boundary  : 
Metadata
Metadata language English
Metadata last updated 15th September 2016
Metadata standard compliance NERC profile of ISO19115:2003
Copyright and IPR
The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.